CS6RE6S12, THE FIRST THIORHENATE WITH A 2 -DIMENSIONAL COUPLING OF [RE6S8] UNITS

Authors
BRONGER W LOEVENICH M SCHMITZ D
Citation
W. Bronger et al., CS6RE6S12, THE FIRST THIORHENATE WITH A 2 -DIMENSIONAL COUPLING OF [RE6S8] UNITS, Journal of alloys and compounds, 216(1), 1994, pp. 25-28
Citations number
11
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
216
Issue
1
Year of publication
1994
Pages
25 - 28
Database
ISI
SICI code
0925-8388(1994)216:1<25:CTFTWA>2.0.ZU;2-E
Abstract
The ternary sulphide Cs6Re6S12 was prepared by combination of caesium carbonate with rhenium in a sulphur-charged argon stream at 800 degree s C. X-Ray investigations of single crystals revealed a two-dimensiona l layered structure which is novel in the field of ternary rhenium cha lcogenides. The compound contains [Re6S8] units linked by monosulphide bridges in accordance with the formula {[Re6S8]S2S4/2}(6-). An analog ous linkage of [M(6)X(8)]-type units is known in MoCl2.