Authors
Citation
W. Bronger et M. Loevenich, RB4RE6S12, SYNTHESIS AND STRUCTURE, Journal of alloys and compounds, 216(1), 1994, pp. 29-32
Citations number
9
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
ISSN journal
09258388
Volume
216
Issue
1
Year of publication
1994
Pages
29 - 32
Database
ISI
SICI code
0925-8388(1994)216:1<29:RSAS>2.0.ZU;2-V
Abstract
The ternary sulphide Rb4Re6S12 was synthesized by the combination of r
ubidium carbonate with rhenium in a sulphur-charged argon stream at 80
0 degrees C. Single-crystal X-ray investigations of this compound reve
aled a structure which is isotypic with those previously reported for
Na4Re6S12 and K4Re6S12. These structures consist of [Re6S8] cluster un
its which are three-dimensionally linked in accordance with the formul
a {[Re6S8]S-4/2((S-2))(2/2)}(4-).