K. Esumi et al., CATALYTIC PROPERTY OF PLATINUM-DISPERSED CARBON PREPARED USING AMPHIPHILIC CARBONACEOUS MATERIALS, Colloids and surfaces. A, Physicochemical and engineering aspects, 94(1), 1995, pp. 93-96
Platinum-dispersed carbon was prepared from amphiphilic carbonaceous m
aterial and [Pt(NH3)4](OH)2 using ammonia water. These reaction mixtur
es gelled and were dried then finally heat-treated. In all the samples
, platinum particle diameters varied from a few nanometers to 20 nm in
the carbon matrix. The platinum-dispersed carbon that had only been h
eat-treated did not exhibit any catalytic activity for hydrogenation o
f cyclohexene. However, activation with CO2 enhanced the catalytic act
ivity, which depended on the activation time and on the Pt loading.