LUMINESCENT EUROPIUM(III) AND TERBIUM(III) IONS ENCAPSULATED IN A 2-AMINOETHOXY OR CARBAMOYLOXY SUBSTITUTED CALIXARENE HOST

Authors
GEORGIEV EM CLYMIRE J MCPHERSON GL ROUNDHILL DM
Citation
Em. Georgiev et al., LUMINESCENT EUROPIUM(III) AND TERBIUM(III) IONS ENCAPSULATED IN A 2-AMINOETHOXY OR CARBAMOYLOXY SUBSTITUTED CALIXARENE HOST, Inorganica Chimica Acta, 227(2), 1994, pp. 293-296
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
227
Issue
2
Year of publication
1994
Pages
293 - 296
Database
ISI
SICI code
0020-1693(1994)227:2<293:LEATIE>2.0.ZU;2-8
Abstract
A series of new 2-aminoethoxy and carbamoyloxy substituted calix[4]are nes and calix[6]arenes has been synthesized and used to complex Eu3+ a nd Tb3+ ions. Emissive complexes in methanol solvent are obtained. The Tb3+ complexes are strongly emissive from a terbium centered excited state. The excited states of the calix[6]arene complexes are less effe ctively quenched by the addition of water than are those having the ca lix[4]arene ligands.