THERMODYNAMIC ANALYSIS OF DICYANOACETYLENE SYNTHESIS BY DEHYDRATION OF ACETYLENEDICARBOXAMIDE WITH PHOSPHORIC ANHYDRIDE IN SELF-PROPAGATINGTHERMAL-WAVE

Authors
ALEKSEEV YI PASHKEVICH DS
Citation
Yi. Alekseev et Ds. Pashkevich, THERMODYNAMIC ANALYSIS OF DICYANOACETYLENE SYNTHESIS BY DEHYDRATION OF ACETYLENEDICARBOXAMIDE WITH PHOSPHORIC ANHYDRIDE IN SELF-PROPAGATINGTHERMAL-WAVE, Russian journal of applied chemistry, 67(1), 1994, pp. 34-37
Citations number
4
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
67
Issue
1
Year of publication
1994
Part
1
Pages
34 - 37
Database
ISI
SICI code
1070-4272(1994)67:1<34:TAODSB>2.0.ZU;2-6
Abstract
The products' composition and heat evolution during the synthesis of d icyanoacetylene by dehydration of acetylenedicarboxamide with phosphor ic anhydride in a self-propagating thermal wave were determined. The t hermodynamic calculations based on these experimental data enabled pro posing the reactions occurring in the thermal wave and the leading sta ge of the wave process.