Av. Zhdanov et al., THERMOELASTIC STRESSES IN RIBBONS AND TUBES GROWN FROM THE MELT BY THE STEPANOV METHOD, Journal of Materials Science, 30(1), 1995, pp. 75-84
Ribbons and tubes grown from the melt by the Stepanov technique have a
wide range of technical applications. Sapphire ribbons are used as su
bstrates in microelectronics and sapphire tubes are used as gas-discha
rge balloons in laser engineering, fine chemical technology and high-v
acuum equipment. Practice has shown that misorientation angles of smal
l-angle boundaries in sapphire crystals should not exceed several degr
ees because an increase in the misorientation angles between blocks dr
astically lowers the strength and worsens the dielectric properties of
these crystals. One of the main mechanisms of formation of the block
structure of melt-grown crystals, including shaped sapphire crystals,
is dislocation polygonization that begins when the dislocation density
exceeds a certain critical value. In turn, dislocations are formed un
der deformations due to thermal stresses. Calculations of thermal fiel
ds in crystals and the corresponding thermoelastic stress fields can b
e used as an input to improve and optimize the growth process. The dep
endence of thermoelastic stresses in ribbons and tubes on the technolo
gical parameters has been calculated.