Waste plastics are an environmental problem because of recycling limit
ations and their resistance to natural decomposition. This research in
vestigates the thermal degradation (pyrolysis) of waste polystyrene in
heavy oil as a tertiary recycling method. Kinetic parameters for pyro
lysis were obtained, and distillate products from the reaction were ch
aracterized by gas chromatography/mass spectroscopy. Four types of hea
vy oil were used to find which would be most suitable in this process.
Complete pyrolysis of polystyrene occurred at temperatures lower than
those reported in the literature.