E. Zhao et al., CALCULATION OF VAPOR-LIQUID-EQUILIBRIA AND SATURATED LIQUID VOLUMES FOR WATER-AMMONIA MIXTURES, Chemical engineering communications, 129, 1994, pp. 99-108
The approach of using T(r) at DELTAZ = Z(V)s - Z(L)s = 0.5 for a balan
ced representation of saturated volumes (V(L)s and V(V)s) of pure comp
onents has been extended from non-polar fluids to water and ammonia. F
or the mixtures of these two compounds, the average absolute percentag
e deviation in the calculated V(L)s values is less than 2% without aff
ecting the representation of vapor-liquid equilibrium values.