GROUP-6 OXYCHLORIDES MOCL(4), WHERE M=MO, W, AND ELEMENT-106 (SG) - ELECTRONIC-STRUCTURE AND THERMOCHEMICAL STABILITY

Authors
PERSHINA V FRICKE B
Citation
V. Pershina et B. Fricke, GROUP-6 OXYCHLORIDES MOCL(4), WHERE M=MO, W, AND ELEMENT-106 (SG) - ELECTRONIC-STRUCTURE AND THERMOCHEMICAL STABILITY, Journal of physical chemistry, 99(1), 1995, pp. 144-147
Citations number
28
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
99
Issue
1
Year of publication
1995
Pages
144 - 147
Database
ISI
SICI code
0022-3654(1995)99:1<144:GOMWMW>2.0.ZU;2-0
Abstract
Results of the Dirac-Slater discrete variational calculations are pres ented for the group 6 oxide tetrachlorides MOCl(4) (M = Mo, W, and ele ment 106 Sg). Estimates of the bond strength have shown that the stabi lity of SgOCl(4) toward thermal decomposition with respect to a loss o f a chlorine atom is of the order of the stability of MoOCl4 losing ch lorine at 25 degrees C. The estimated formation enthalpy of SgOCl(4) o f -114 +/- 6 kcal/mol is less negative than those of the lighter homol ogs.