SILVER OXALATE, 2AG(+).C2O42-

Authors
NAUMOV DY VIROVETS AV PODBEREZSKAYA NV BOLDYREVA EV
Citation
Dy. Naumov et al., SILVER OXALATE, 2AG(+).C2O42-, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 60-62
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
1
Pages
60 - 62
Database
ISI
SICI code
0108-2701(1995)51:<60:SO2>2.0.ZU;2-4
Abstract
The early data of Griffith [J. Chem. Phys, (1943), pp. 499-505] and of Kolesnikov & Baumer [Vestn. Khar'k. Univ. Ser. Khim. (1975), 127, 38- 41] on the structure of silver oxalate, 2Ag(+).C2O42-, are revised and refined. In the structure, the oxalate anions form a framework with c hannels extended along [100] and Ag+ cations are located in these chan nels, forming dimers with an Ag-Ag bond distance of 2.945 (1)Angstrom (close to that in metallic Ag). A noticeable elongation of C-C bond is observed.