HLOROBIS(N,N-DIETHYLDITHIOCARBAMATO)(VINYL)TIN(IV)

Authors
VRABEL V KELLO E HOLECEK J SIVY J LOKAJ J
Citation
V. Vrabel et al., HLOROBIS(N,N-DIETHYLDITHIOCARBAMATO)(VINYL)TIN(IV), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 70-72
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
1
Pages
70 - 72
Database
ISI
SICI code
0108-2701(1995)51:<70:H>2.0.ZU;2-T
Abstract
The crystal structure of the title compound, [SnCl(C2H3)(C5H10NS2)(2)] , consists of relatively isolated complex molecules, the closest inter molecular contact [3.573 (6) Angstrom] being between the methyl C atom C(3) and the S atom S(2) of neighbouring molecules. The Sn atom is he xacoordinated by the vinyl group, the Cl atom and the two bidentate di thiocarbamate ligands, resulting in a distorted octahedral geometry. T he vinyl group and Cl atom both occupy cis positions with respects to the dithiocarbamate ligands.