Ta. Jurgens et Jw. Rogers, REACTIONS OF TETRAETHOXYSILANE VAPOR ON POLYCRYSTALLINE TITANIUM-DIOXIDE, Journal of physical chemistry, 99(2), 1995, pp. 731-743
The reactions of tetraethoxysilane (TEOS) vapor on dehydroxylated and
water predosed polycrystalline TiO2 were studied by Fourier transform
infrared spectroscopy (FTIR) and temperature-programmed desorption (TP
D). Exposure at 300 K leads to dissociative adsorption producing a mon
oethoxysilyl ligand and surface ethoxide species. The ethoxide ligands
react and desorb in the range 450-650 K as gas phase ethanol and ethy
lene, while the monoethoxysilyl ligand decomposes at similar to 650 K
to gas phase ethanol and ethylene and surface bound SiO2. Dissociation
of TEOS on TiO2 is not affected by water predose; although, a greater
amount of ethanol is produced in the gas phase at 550-650 K, and the
SiO2 which is formed exhibits vibrational features characteristic of a
hydroxylated species. TEOS chemistry on TiO2 was compared to, the ads
orption and reaction of ethanol on the same surface. Adsorption of eth
anol at 300 K yielded surface ethoxide species which desorbed in two s
tates as the parent alcohol and ethylene; desorption was also centered
at 450 and 650 K. These results complement and supplement our previou
s study of TEOS on a TiO2(110) single crystal surface.