FORMATION OF INTERCALATION COMPOUNDS OF A LAYERED SODIUM OCTOSILICATEWITH N-ALKYLTRIMETHYLAMMONIUM IONS AND THE APPLICATION TO ORGANIC DERIVATIZATION

Authors
ENDO K SUGAHARA Y KURODA K
Citation
K. Endo et al., FORMATION OF INTERCALATION COMPOUNDS OF A LAYERED SODIUM OCTOSILICATEWITH N-ALKYLTRIMETHYLAMMONIUM IONS AND THE APPLICATION TO ORGANIC DERIVATIZATION, Bulletin of the Chemical Society of Japan, 67(12), 1994, pp. 3352-3355
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
67
Issue
12
Year of publication
1994
Pages
3352 - 3355
Database
ISI
SICI code
0009-2673(1994)67:12<3352:FOICOA>2.0.ZU;2-S
Abstract
In this study, n-alkyltrimethylammonium ions ([CnH2n+N-1(CH3)(3)](+); n=12, 14, 16, 18) were intercalated in the interlayer space of layered sodium octosilicate (Na2Si8O17.nH(2)O) via an ion-exchange reaction. The interlayer space was further modified by grafting of the trimethyl silyl groups via a reaction between a dodecyltrimethylammonium-octosil icate intercalation compound and chlorotrimethylsilane.