MAGNETIC-SUSCEPTIBILITIES OF AQUEOUS-SOLUTIONS OF THE COPPER(II) COMPOUNDS WITH OMEGA-PYRIDINIOCARBOXYLATE

Authors
EMORI S DATE C
Citation
S. Emori et C. Date, MAGNETIC-SUSCEPTIBILITIES OF AQUEOUS-SOLUTIONS OF THE COPPER(II) COMPOUNDS WITH OMEGA-PYRIDINIOCARBOXYLATE, Bulletin of the Chemical Society of Japan, 67(12), 1994, pp. 3360-3362
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
67
Issue
12
Year of publication
1994
Pages
3360 - 3362
Database
ISI
SICI code
0009-2673(1994)67:12<3360:MOAOTC>2.0.ZU;2-I
Abstract
Copper(II) compounds: CuCl2[C5H5NCH2COO].3H(2)O, CuCl2[C5H5N(CH2)(n)CO O].2H(2)O (n=2, 3), and CuCl2[C5H5N(CH2)(n)COO](2) (n=1-3) were prepar ed. Then they were characterized by means of magnetic susceptibility a nd IR spectroscopy. The equilibria between mono- and dinuclear species in their aqueous solutions were studied using magnetic susceptibility measurements. The tendency for adopting dinuclear species in water in creased in the order: acetate<3-pyridiniopropionate<4-pyridiniobutyrat e.