THERMODYNAMICS AND KINETIC-PROPERTIES OF C IN NI-FE-C SOLID-SOLUTIONS

Citation
Rb. Mclellan et L. Yang, THERMODYNAMICS AND KINETIC-PROPERTIES OF C IN NI-FE-C SOLID-SOLUTIONS, Journal of physics and chemistry of solids, 55(11), 1994, pp. 1227-1232
Citations number
23
Categorie Soggetti
Physics, Condensed Matter",Chemistry
ISSN journal
00223697
Volume
55
Issue
11
Year of publication
1994
Pages
1227 - 1232
Database
ISI
SICI code
0022-3697(1994)55:11<1227:TAKOCI>2.0.ZU;2-V
Abstract
Solid solutions of C in the f.c.c. Ni-Fe matrix exhibit an anomaly whi ch manifests itself in a peak in the variation of the activation energ y for diffusion and the partial enthalpy of the dissolved C-atoms with the composition of the Ni-Fe matrix. This peak, which occurs at about 0.25-0.3 at. % Fe, has been shown to be primarily related to volume c hanges in the Ni-Fe matrix rather than to effects related to the elect ronic states of Fe atoms.