SILICA-GELS MADE BY BICONTINUOUS MICROEMULSION POLYMERIZATION

Microporous silica gels can be made by polymerizing partially hydrolyz ed tetramethoxysilane sols present in the aqueous phase of bicontinuou s microemulsions stabilized with didodecyldimethylammonium bromide. Th en vacuum-dried, the gels made in microemulsions have about twice the specific surface area of conventional vacuum-dried silica gets. They h ave 70% of the specific area of supercritically dried gels. Small-angl e X-ray scattering measurements in these gels show two characteristic sizes. One size, around 24 Angstrom, in the original microemulsion is retained during polymerization, but lost when the detergent is extract ed. The second size grows with the square root of time during the poly merization, suggesting diffusion-controlled gelation.