THE 3RD-ORDER OPTICAL NONLINEARITY OF THE PHENYLETHYNYL-SUBSTITUTED BENZENE SYSTEM

Authors
KONDO K YASUDA S SAKAGUCHI T MIYA M
Citation
K. Kondo et al., THE 3RD-ORDER OPTICAL NONLINEARITY OF THE PHENYLETHYNYL-SUBSTITUTED BENZENE SYSTEM, Journal of the Chemical Society, Chemical Communications, (1), 1995, pp. 55-56
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
1
Year of publication
1995
Pages
55 - 56
Database
ISI
SICI code
0022-4936(1995):1<55:T3ONOT>2.0.ZU;2-R
Abstract
Phenylethynyl substituted benzenes 1, 2 and 3 are synthesized by the P d-coupling reaction of phenylacetylene with the corresponding bromoben zene; the third-order optical non-linearity [chi((3))(omega)] increase s with the participation of pi-conjugation through the triple bond as determined by the degenerate four-wave mixing (DFWM) method in a chlor oform solution.