L. Papahagi et al., POLYMETALLIC CATALYSTS INFLUENCE UPON THE QUALITY OF THE SYNTHETIC FATTY-ACIDS RESULTING FROM THE N-ALCANES OXIDATION, Revista de chimie, 47(9), 1996, pp. 806-810
Tbe polymetallic catalysts effect in increasing the n-dodecane liquid
- phase oxidation process selectivity was studied. It was found that,
by introducing a third component - e.g. Co - in the usual Mn+K catalys
t, the ester index decreases by approximately 2 times, while the hydro
xyl and carbonyl indexes decrease 4-5 times as compared to the bicompo
nent catalyst, Therefore it contributes to improve the synthetic fatty
acids quality by decreasing the polyfunctional, hydroacid and cetoaci
d derivatives content.