Mn. Hounkonnou et P. Navez, ROTATIONAL BROWNIAN-MOTION OF A 2-DIMENSIONAL RIGID ROTATOR - RELAXATION AND STEADY-STATE REGIMES, Journal of the Chemical Society. Faraday transactions, 91(1), 1995, pp. 41-50
Citations number
19
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Exact analytical expressions for the dielectric and Kerr functions in
both relaxation and steady-state regimes are explicitly calculated by
solving the Fokker-Planck-Kramers (FPK) equation for the rotational Br
ownian motion of a rigid rotator in 2D. The response functions which a
re thus obtained, generalize and extend all the results recently publi
shed on the topic. The particular case of the Debye-Smoluchowski diffu
sion model is straighfforwardly recovered. We give also the entropy fo
rmula for the rotator system and analyse the implication of the second
principle of thermodynamics for the steady-state dielectric and Kerr
functions.