SYNTHESIS AND CHARACTERIZATION OF THE ENCAPSULATED STANNOCENES [(C3H7)(3)C5H2]SN-2 AND [(C3H7)(4)C5H]SN-2

Authors
BURKEY DJ HANUSA TP
Citation
Dj. Burkey et Tp. Hanusa, SYNTHESIS AND CHARACTERIZATION OF THE ENCAPSULATED STANNOCENES [(C3H7)(3)C5H2]SN-2 AND [(C3H7)(4)C5H]SN-2, Organometallics, 14(1), 1995, pp. 11-13
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
1
Year of publication
1995
Pages
11 - 13
Database
ISI
SICI code
0276-7333(1995)14:1<11:SACOTE>2.0.ZU;2-P
Abstract
The encapsulated stannocenes [(C3H7)(4)C5H]Sn-2 and [(C3H7)(3)C5H2]Sn- 2 are isolated as an, air-stable, high-melting solid and an air-sensit ive oil, respectively; their physical properties mirror those of alkal ine-earth metallocenes containing these ligands. The X-ray crystal str ucture of [(C3H7)(4)C5H]Sn-2 reveals a bent-metallocene geometry close ly related to that of [(C3H7)(4)C5H]Ca-2