INFLUENCE OF DIFFERENT 4,7-SUBSTITUTED 1,10-PHENANTHROLINE LIGANDS ONREACTIVITY AND REGIOCONTROL AND STEREOCONTROL IN TUNGSTEN-CATALYZED ALLYLIC ALKYLATIONS
H. Frisell et B. Akermark, INFLUENCE OF DIFFERENT 4,7-SUBSTITUTED 1,10-PHENANTHROLINE LIGANDS ONREACTIVITY AND REGIOCONTROL AND STEREOCONTROL IN TUNGSTEN-CATALYZED ALLYLIC ALKYLATIONS, Organometallics, 14(1), 1995, pp. 561-563
The substitution of allylic carbonate using tetracarbonyl(1,10-phenant
hroline)tungsten(0) complexes as catalysts was found to give products
with high retention of configuration (>90%) with both (E)- and (Z)-sub
strates.