INFLUENCE OF DIFFERENT 4,7-SUBSTITUTED 1,10-PHENANTHROLINE LIGANDS ONREACTIVITY AND REGIOCONTROL AND STEREOCONTROL IN TUNGSTEN-CATALYZED ALLYLIC ALKYLATIONS

Citation
H. Frisell et B. Akermark, INFLUENCE OF DIFFERENT 4,7-SUBSTITUTED 1,10-PHENANTHROLINE LIGANDS ONREACTIVITY AND REGIOCONTROL AND STEREOCONTROL IN TUNGSTEN-CATALYZED ALLYLIC ALKYLATIONS, Organometallics, 14(1), 1995, pp. 561-563
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
02767333
Volume
14
Issue
1
Year of publication
1995
Pages
561 - 563
Database
ISI
SICI code
0276-7333(1995)14:1<561:IOD41L>2.0.ZU;2-V
Abstract
The substitution of allylic carbonate using tetracarbonyl(1,10-phenant hroline)tungsten(0) complexes as catalysts was found to give products with high retention of configuration (>90%) with both (E)- and (Z)-sub strates.