Recent results on the substitutional Au and interstitial Fe deep-level
impurities in silicon are discussed in some detail. Their excitation
spectra are due to transitions from a deep ground state to shallow sta
tes. The good understanding of the electronic structure of the shallow
states as well as their response to external perturbations, i.e., uni
axial stress and magnetic field, allows for a detailed investigation o
f the electronic structure of the deep states.