Phenomena due to existence of longliving excited states of some III an
d V group impurities in Si are considered. The dependences of extrinsi
c photoconductivity under microwave bias on excitation intensity, temp
erature, majority and minority impurity concentration are explained by
the model of polarization hopping photoconductivity. A strong influen
ce of background radiation intensity on infrared absorption by longliv
ing excited states is observed. Absorption spectra of longliving excit
ed states of B and As impurities are obtained.