D. Forkelwirth et al., HYDROGEN PASSIVATION OF CD-ACCEPTORS IN III-V-SEMICONDUCTORS STUDIED BY PAC SPECTROSCOPY, Solid state communications, 93(5), 1995, pp. 425-430
Formation, structure, and stability of hydrogen correlated complexes,
created at Cd accepters in GaP, InP, and InAs have been studied after
plasma charging as well as after H+ and/or He+ implantation at differe
nt energies. The different complexes were monitored by the perturbed a
ngular correlation technique (PAC). In InP and GaP, the stability of C
d-H pairs is very similar for comparable Cd concentrations (E(D) = 1.4
(2) eV and E(D) = 1.5(1) eV). In InAs, two different hydrogen correlat
ed configurations are observed, one could be identified as Cd-H pair,
oriented in [111] lattice direction (v(Q) = 427 MHz, eta = 0). The sec
ond complex involves at least one H atom and radiation defects or, fav
oured by a defect induced, secondary mechanism several hydrogen atoms.