Jlf. Goldstein et Jw. Morris, THE EFFECT OF SUBSTRATE ON THE MICROSTRUCTURE AND CREEP OF EUTECTIC IN-SN, Metallurgical and materials transactions. A, Physical metallurgy andmaterials science, 25(12), 1994, pp. 2715-2722
This study was conducted in order to determine and understand the effe
ct of substrate on the behavior of eutectic In-Sn. Samples for mechani
cal testing were produced with either bare Cu or Ni on Cu substrates.
Both the microstructure and the mechanical behavior are strongly depen
dent on substrate. When eutectic In-Sn is joined to bare Cu, Cu diffus
ion into the joint causes the alloy to become off-eutectic, giving a n
onuniform and irregular microstructure. The addition of a layer of Ni
acts as a diffusion barrier, preventing Cu diffusion sufficiently such
that a uniform, normal colony-based eutectic forms. Deformation is mo
re uniform in the In-Sn on Ni, while it is concentrated along the leng
th of the joint in the In-Sn on Cu. This distinction is reflected in t
he different shapes of shear stress-strain curves between In-Sn on Cu
and In-Sn on Ni. The stress exponents and activation energies for cree
p also vary with substrate. Creep deformation is governed by the In-ri
ch beta phase for In-Sn on Cu and by the Sn-rich gamma phase for In-Sn
on Ni. If In-Sn on Ni samples are aged, the microstructure coarsens a
nd the mechanical behavior changes to resemble that of the as-cast In-
Sn on Cu.