KINETICS AND MECHANISM OF THE SYNTHESIS OF DIFLUOROBENZENES BY THERMAL-REACTION OF DIFLUOROCARBENE WITH BUTADIENE

Authors
SHIPILOV AI ZABOLOTSKIKH VF NEFEDOV OM
Citation
Ai. Shipilov et al., KINETICS AND MECHANISM OF THE SYNTHESIS OF DIFLUOROBENZENES BY THERMAL-REACTION OF DIFLUOROCARBENE WITH BUTADIENE, Russian journal of applied chemistry, 67(1), 1994, pp. 77-85
Citations number
10
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
67
Issue
1
Year of publication
1994
Part
2
Pages
77 - 85
Database
ISI
SICI code
1070-4272(1994)67:1<77:KAMOTS>2.0.ZU;2-S
Abstract
Reaction of butadiene with difluorocarbene, resulting in the formation of difluorobenzenes, and its main steps have been systematically stud ied. The kinetics of thermal conversions of intermediately formed 2,2- difluorovinylcyclopropane and 2,2,3,3-tetrafluorovinylcyclobutane has been examined. The synthesis of difluorobenzenes has been optimized. T he results obtained are used as a basis for domestic technology of pro duction of difluorobenzenes.