FLUORINATION OF METHANE AND ITS FLUORINE DERIVATIVES BY COBALT TRIFLUORIDE

Authors
ASOVICH VS KORNILOV VV KOSTYAEV RA MAKSIMOV VN
Citation
Vs. Asovich et al., FLUORINATION OF METHANE AND ITS FLUORINE DERIVATIVES BY COBALT TRIFLUORIDE, Russian journal of applied chemistry, 67(1), 1994, pp. 94-96
Citations number
4
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
67
Issue
1
Year of publication
1994
Part
2
Pages
94 - 96
Database
ISI
SICI code
1070-4272(1994)67:1<94:FOMAIF>2.0.ZU;2-6
Abstract
Fluorination of methane is studied with the aim of using difluorometha ne and trifluoromethane as promising ozone-safe refrigerants. Principa l kinetic features of fluorination of methane, difluoromethane, and tr ifluoromethane in gas phase are determined. Activation energies and pr eexponential factors of the rate constants of the main reactions are p resented. The process studied is shown to be promising for industrial production of fluoromethanes.