FLUORINATION OF ETHYLENE BY HIGHER FLUORIDES OF COBALT, MANGANESE, AND CERIUM

Authors
ASOVICH VS KORNILOV VV MAKSIMOV BN
Citation
Vs. Asovich et al., FLUORINATION OF ETHYLENE BY HIGHER FLUORIDES OF COBALT, MANGANESE, AND CERIUM, Russian journal of applied chemistry, 67(1), 1994, pp. 97-100
Citations number
8
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
67
Issue
1
Year of publication
1994
Part
2
Pages
97 - 100
Database
ISI
SICI code
1070-4272(1994)67:1<97:FOEBHF>2.0.ZU;2-9
Abstract
Fluorination of ethylene by higher fluorides of metals with variable v alence (CoF3, CeF4, MnF3) is studied. Temperature dependences of the c ontents of fluorinated products are obtained. The mechanism of formati on of significant amounts of 1,1,1,2-tetrafluoroethane in the reaction involving CoF3 and oligomers in the reaction involving CeF4, is propo sed.