RADICAL REACTIONS OF 6,6-DIMETHYLFULVENE AT PARAMAGNETIC COBALT(0) CENTERS STRUCTURE OF A DICOBALT COMPLEX CONTAINING A TETRAMERIC HYDROCARBON LIGAND

Authors
KLEIN HF AUER E JUNG T ROHR C KNIEP R
Citation
Hf. Klein et al., RADICAL REACTIONS OF 6,6-DIMETHYLFULVENE AT PARAMAGNETIC COBALT(0) CENTERS STRUCTURE OF A DICOBALT COMPLEX CONTAINING A TETRAMERIC HYDROCARBON LIGAND, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(12), 1994, pp. 1684-1688
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
12
Year of publication
1994
Pages
1684 - 1688
Database
ISI
SICI code
0932-0776(1994)49:12<1684:RRO6AP>2.0.ZU;2-E
Abstract
6,6-Dimethylfulvene reacts with CO(C2H4)(PMe(3))(3) to give a diamagne tic dicobalt complex containing a novel bis (eta(5),eta(2))-chelating hydrocarbon ligand which is a tetramer of 6,6-dimethylfulvene. C,C-cou pling via radicals induces multiple chirality in the ligand and the st ructurally characterized stereoisomer adopts a (S,R,R,S) configuration (meso form).