CUBANE DERIVATIVES .1. SYNTHESIS AND MOLECULAR-STRUCTURES OF THE ESTERS OF 1,4-CUBANEDICARBOXYLIC ACID

Authors
EREMENKO LT ROMANOVA LB IVANOVA ME EREMENKO IL NEFEDOV SE STRUCHKOV YT
Citation
Lt. Eremenko et al., CUBANE DERIVATIVES .1. SYNTHESIS AND MOLECULAR-STRUCTURES OF THE ESTERS OF 1,4-CUBANEDICARBOXYLIC ACID, Russian chemical bulletin, 43(4), 1994, pp. 619-623
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
4
Year of publication
1994
Pages
619 - 623
Database
ISI
SICI code
1066-5285(1994)43:4<619:CD.SAM>2.0.ZU;2-V
Abstract
An effective method of esterification of 1,4-cubanedicarboxylic acid w ith alkylsulfuric acids is proposed. The derivatives of alkanols with substantially different pK(a) values are obtained in high yields. Mole cular structures of the esters obtained are confirmed by various metho ds. The X-ray study showed a remarkable effect of the nature of an alk yl radical on the geometry of the cubane core.