HYPERCOORDINATED COMPOUNDS OF GOLD(I) .1. SYNTHESIS AND PROPERTIES OFMONONUCLEAR AND BINUCLEAR ORGANOGOLD(I) DERIVATIVES OF DIPHENYL ETHER

Authors
BAUKOVA TV OLEINIKOVA NA LEMENOVSKII DA KUZMINA LG
Citation
Tv. Baukova et al., HYPERCOORDINATED COMPOUNDS OF GOLD(I) .1. SYNTHESIS AND PROPERTIES OFMONONUCLEAR AND BINUCLEAR ORGANOGOLD(I) DERIVATIVES OF DIPHENYL ETHER, Russian chemical bulletin, 43(4), 1994, pp. 681-688
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
4
Year of publication
1994
Pages
681 - 688
Database
ISI
SICI code
1066-5285(1994)43:4<681:HCOG.S>2.0.ZU;2-K
Abstract
Mono- and binuclear gold(I) derivatives of ortho-substituted diphenyl ether, C(6)H(5)OC(6)H(4)AuPPh(3) and O(C6H4)(2)(AuPPh(3))(2), were pre pared by the reaction of the 2,2'-dilithium derivative of diphenyl eth er with ClAuPPh(3). X-Ray structural study has shown that these compou nds contain secondary intramolecular bonds between the gold and oxygen atoms. The interaction of C(6)H(5)OC(6)H(4)AuPPh(3) with (AuPPh(3))BF 4 affords the [C6H5OC6H4(AuPPh(3))(2)]BF4 cationic complex. The fatter reacts with PPh(3) to give the starting C(6)H(5)OC(6)H(4)AuPPh(3) com plex.