CHEMILUMINESCENCE BY THE INTERACTION OF XEO3 AND THE PRODUCTS OF PHOTOLYSIS OF URANYL SOLUTIONS IN SULFURIC-ACID

Authors
KHAMIDULLINA LA LOTNIK SV KAZAKOV VP
Citation
La. Khamidullina et al., CHEMILUMINESCENCE BY THE INTERACTION OF XEO3 AND THE PRODUCTS OF PHOTOLYSIS OF URANYL SOLUTIONS IN SULFURIC-ACID, Russian chemical bulletin, 43(4), 1994, pp. 704-707
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
4
Year of publication
1994
Pages
704 - 707
Database
ISI
SICI code
1066-5285(1994)43:4<704:CBTIOX>2.0.ZU;2-Y
Abstract
Using the chemiluminescence oxidation of U(IV) and H2O2 with xenon tri oxide as a model, it has been found that during the photolysis of solu tions of UO2SO4 in sulfuric acid in the absence of any organic compoun ds, the accumulation of U(SO4)(2) and H2O2 takes place as a result of the reaction of the primary products of the photoreduction of uranyl i on, i.e., UO2+ and the .OH radical.