Several solid solutions of the mixed crystalline Fe1-xVxF3 series; syn
thesized by the solid-state reaction, are investigated by Mossbauer sp
ectroscopy. The evolution of the hyperfine structure as a function of
temperature suggests that the Fe0.50V0.50F3 compound exhibits a spin-c
lustering phenomenon over the temperature range 70-175 K. We report he
re some preliminary high field Mossbauer spectra in order to discuss t
he magnetic behaviour.