SYNTHESIS OF ALDEHYDES FROM ACYL CHLORIDES VIA 1-(ACYLMETHYLAMINO)-3-METHYLIMIDAZOLIUM SALTS

Authors
DELASHERAS MA VAQUERO JJ GARCIANAVIO JL ALVAREZBUILLA J
Citation
Ma. Delasheras et al., SYNTHESIS OF ALDEHYDES FROM ACYL CHLORIDES VIA 1-(ACYLMETHYLAMINO)-3-METHYLIMIDAZOLIUM SALTS, Tetrahedron letters, 36(3), 1995, pp. 455-458
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
3
Year of publication
1995
Pages
455 - 458
Database
ISI
SICI code
0040-4039(1995)36:3<455:SOAFAC>2.0.ZU;2-W
Abstract
The reaction of acyl chlorides with 1-amino-3-methylimidazolium salts, followed by N-methylation of the resulting H-aminides, afforded 1-(ac ylmethylamino)-3-methylimidazolium salts which, upon treatment with DI BALHgave aldehydes in good yields. A nalogously, dialdehydes were obta ined from the corresponding bis-salts.