Jmr. Genin et al., PRODUCTS OBTAINED BY MICROBIALLY-INDUCED CORROSION OF STEEL IN A MARINE-ENVIRONMENT - ROLE OF GREEN RUST 2, Hyperfine interactions, 93(1-4), 1994, pp. 1807-1812
An unusual low-water corrosion of steel sheet piles has been systemati
cally investigated in a channel harbour (Boulogne sur Mer, France), An
analysis of the environment reveals that all sampling of dark rust ta
ken at different heights above marine sediments and kept in anaerobic
conditions present unusual concentrations of sulfate-reducing bacteria
. The rust products have been characterized by Mossbauer spectroscopy
and Xray diffraction, comprising the ferrous-ferric sulfated compounds
of formula 4Fe(OH)(2).2FeOOH.FeSO4.nH(2)O, called green rust 2, mixed
sometimes with magnetite and a small amount of ferrous sulfide.