Mossbauer spectra are presented at 15 and 298 K for magnetically-separ
ated extracts of magnetic soils from a tuffite-derived weathering mant
le from Minas Gerais, Brazil. The principal iron-bearing mineral is ma
ghemite in which the degree of Ti or Mg substitution is found to vary
with depth. The Mg-maghemite, with lattice parameter a(0) = 0.838 nm,
is a new natural mineral. It is associated with anatase in the magneti
c-separates.