Fs. Li et al., FE-57 HIGH-PRESSURE MOSSBAUER AND X-RAY STUDIES OF GD2FE17CX INTERSTITIAL COMPOUNDS, Hyperfine interactions, 94(1-4), 1994, pp. 1959-1964
The unit cell volume dependence of the Curie temperature of Gd2Fe17 is
studied by means of high-pressure Mossbauer spectroscopy. From the pr
essure dependence of the average isomer shift of Ge2Fe17 at room tempe
rature, the contribution of the pure magnetovolume effect to the chang
e of the average isomer shift is derived. By combining the Mossbauer m
easurements of Gd2Fe17Cx with different C concentrations at room tempe
rature, the change of IS in Gd2Fe17Cx is dominated by the magnetovolum
e effect. The contribution of the chemical bonding effect is about 24%
of that of the magnetovolume effect, but with negative sign.