Three interplanetary dust particles (IDPs) collected in the stratosphe
re were analyzed with imaging time-of-flight secondary ion mass spectr
ometry (TOF-SIMS) to investigate the elemental distribution within the
se particles at high lateral resolution and to demonstrate the abiliti
es of this new technique for the analysis of IDPs and other microsampl
es. This study should furthermore show that it is possible to correlat
e TOF-SIMS data and TEM observations of the same interplanetary dust p
article. Element ratios for 15 different elements relative to Si were
determined using SIMS sensitivities from analyses of several standards
. The TOF-SIMS results show inhomogeneous distribution and large devia
tions from chondritic abundances for several elements in IDP U2015G1 w
hereas W7029A27 and L2005P9 show chondritic element ratios and a rela
tively homogeneous distribution, respectively. These results, which ar
e comparable with previous results obtained by different techniques, d
emonstrate the reliability of TOF-SIMS, even for quantitative measurem
ents. In U2015G1 halogen and sulphur enrichments were observed in an e
xtremely fine-grained Fe oxide phase. This can easily be explained by
contamination processes in the stratosphere.