MOLECULAR-BEAM SCATTERING BY A SURFACE IN THE PARTIALLY ROUGH SPHERE MODEL

Citation
Ap. Blokhin et Mf. Gelin, MOLECULAR-BEAM SCATTERING BY A SURFACE IN THE PARTIALLY ROUGH SPHERE MODEL, Surface science, 323(3), 1995, pp. 323-332
Citations number
25
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00396028
Volume
323
Issue
3
Year of publication
1995
Pages
323 - 332
Database
ISI
SICI code
0039-6028(1995)323:3<323:MSBASI>2.0.ZU;2-D
Abstract
The partially rough sphere model is adopted to study rototranslational dynamics of molecule-surface scattering. Analytical expressions for d istributions over linear and angular velocities are derived and averag ed energies are calculated. The model allows to investigate the tangen tial force influence on the outgoing molecular beam characteristics an d describes out-of-plane scattering and nonzero 'orientation'. The eff ect of the attractive branch of the molecule-surface potential and the generalization of the model on trapping-desorption processes are also discussed.