CETYLTRIMETHYLAMMONIUM CHLOROCHROMATE (CTACC)-T-BUTYL HYDROPEROXIDE (TBHP) - A CONVENIENT OXIDATION REAGENT

Citation
Dd. Agarwal et al., CETYLTRIMETHYLAMMONIUM CHLOROCHROMATE (CTACC)-T-BUTYL HYDROPEROXIDE (TBHP) - A CONVENIENT OXIDATION REAGENT, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 34(2), 1995, pp. 158-160
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03764699
Volume
34
Issue
2
Year of publication
1995
Pages
158 - 160
Database
ISI
SICI code
0376-4699(1995)34:2<158:CC(H(>2.0.ZU;2-2
Abstract
An efficient chromium (VI) catalyst cetyltrimethyl-ammonium chlorochro mate (CTACC) in combination with t-butyl hydroperoxide (TBHP) effects excellently the epoxidation of olefins, oxidation of secondary alcohol s to carbonyl compounds and various allylic and benzylic oxidations. S ome successful stoichiometric oxidations of olefins have been studied.