The interaction of slow highly charged ions with many-electron targets
leads to the formation of unstable, multiply excited projectiles. We
simulated the formation of such hollow ions for slow incident Bi46+ pr
ojectiles and C-60 targets. Our semiclassical overbarrier simulation i
ncludes resonant exchange and Auger emission of electrons. It models t
he dynamical variation of level occupations and charge states during t
he collision and predicts highly unstable hollow ions immediately afte
r the collision. With respect to the subsequent downstream relaxation
of the hollow ions, we propose a simple relaxation scheme that include
s autoionizing and radiative transitions. As a consequence of this dow
nstream relaxation, almost all of the resonantly captured electrons ar
e emitted.