For micro- and mesoporous silicon samples a decrease in conductivity b
y several orders of magnitude as compared with the substrate is observ
ed. Since the structures in mesoporous silicon are too large to show s
ignificant quantum confinement, models for the decreased conduction ba
sed on quantum confinement are not applicable. A new model for the cha
rge transport mechanism based on constrictions of conductive pathways
produced by charged surface traps is proposed and verified in experime
nts.