The electroless and cathodic electrodeposition of metals (Au, Cu, Ni)
into porous silicon (PS) is studied. The electrochemically modified PS
layers are analysed by X-ray photoelectron spectroscopy and sputter d
epth profiling. The electroless deposition oxidizes PS simultaneously.
For this reaction a new concept of injection current multiplication i
s proposed. After cathodic metal deposition the pores are filled with
metal quantitatively without oxidation of PS.