Porous silicon exhibits a fast (similar to 1 ns) luminescence band in
the blue-green (2.3-2.7 eV) spectral region when post-treated by rapid
thermal oxidation. In addition we observe for the blue emission a tim
e-delayed signal with a typical time constant of order 1 s that indica
tes carrier trapping. This component is present at low temperatures an
d has a sharp excitation onset at 4.3 eV. Quenching of the slow signal
after additional thermal treatment of aged samples is accompanied by
changes in the IR spectrum.