Electron powder ribbon (EPR) plates elaborated from 99.9%-99.9999% pur
e silicon powder show crystallographic structure favourable to the ach
ievement of nanocrystallites which are at the origin of luminescence.
Fourier transform IR spectrometry and secondary ion mass spectrometry
observations correlated with the comparative luminescence of porous la
yers produced on single-crystal and EPR polycrystalline silicon are ca
rried out. The luminescence spectra are controlled by a combination of
the electrochemical parameters and the starting material resistivity.
An electroluminescent cell is elaborated and microcrystalline structu
res are obtained for sensor applications using the adsorption process
(e.g. moisture measurements).