V. Petrovakoch et T. Muschik, THE RELATION BETWEEN THE VISIBLE AND THE INFRARED LUMINESCENCE BANDS IN POROUS SILICON - COMPARISON WITH AMORPHOUS SI ALLOYS, Thin solid films, 255(1-2), 1995, pp. 246-249
The energy positions of the visible and the infrared luminescence band
s in porous Si are related. Their dependence on different parameters i
s examined. They are both blue-shifted (from 1.0 eV to 2.1 eV for the
visible and from 0.8 eV to 1.3 eV for the infrared band) due to a redu
ced crystallite size. However, the visible band can be red-shifted by
up to 300 meV by surface effects. The observed behaviour is characteri
stic of neither pure quantum systems nor amorphous alloys. It is typic
al for porous Si containing surface slates.