The study of the steady state and transient photoconductivity (PC) of
p- and n-type porous silicon (PS) self-supporting layers allows us to
eliminate the influence of a crystalline Si substrate on the PC. A pho
tovoltaic effect was observed in sandwich geometry for short wavelengt
h illumination and for long wavelengths (similar or equal to 580 nm) a
broad photoconductive maximum was found. An explanation of both effec
ts is proposed. Transient photoconductivity has revealed a redistribut
ion of the inner electric field after 1-10 ms and it is proposed here
as a new tool for the study of PS.