R. Kudesia et al., EFFECTS OF LA2O3 ZNO ADDITIVES ON MICROSTRUCTURE AND MICROWAVE DIELECTRIC-PROPERTIES OF ZR0.8SN0.2TIO4 CERAMICS, Journal of the American Ceramic Society, 77(12), 1994, pp. 3215-3220
Dielectric ceramics of Zr0.8Sn0.2TiO4 containing La2O3 and ZnO as sint
ering aids were prepared and investigated for microstructure and micro
wave dielectric properties. Low-level doping with La2O3 and ZnO (up to
0.30 wt%) is good for densification and dielectric properties. These
additives do not affect the dielectric constant and the temperature co
efficient. Dielectric losses increase significantly at additive levels
higher than 0.15 wt%. The combined additives La2O3 and ZnO act as gra
in growth enhancers. With 0.15 wt% additives, a ceramic having a diele
ctric constant, a quality factor, and a temperature coefficient of fre
quency at 4.2 GHz of 37.6, 12800, and -2.9 ppm/degrees C, respectively
, was obtained. The quality factor was considerably improved by prolon
ged sintering.