Ta. Fuller et al., A 2-TEMPERATURE MODEL OF THE REGENERATIVE SOLID-VAPOR HEAT-PUMP, Journal of offshore mechanics and Arctic engineering, 116(4), 1994, pp. 297-304
A thermally driven heat pump using a solid/vapor adsorption/desorption
compression process is thermodynamically analyzed. Heat regeneration
between the two adsorbent beds is accomplished through the use of a ci
rculating heat transfer (HX) fluid. Effective heat regeneration and sy
stem performance requires that steep thermal profiles or waves be esta
blished in the beds along the path of the HX-fluid flow direction. Pre
vious studies by Shelton, Wepfer, and Miles have used square and ramp
profiles to approximate the temperature profiles in the adsorbent beds
, which, in turn, enable the thermodynamic performance of the heat pum
p to be computed. In this study, an integrated heat transfer and therm
odynamic model is described The beds are modeled using a two-temperatu
re approach. A partial differential equation for the lumped adsorbent
bed and tube is developed to represent the bed temperature as a functi
on of time and space (along the flow direction), while a second partia
l differential equation is developed for the heat transfer fluid to re
present the fluid temperature as a function of time and space (along t
he flow direction). The resulting differential equations are nonlinear
due to pressure and temperature-dependent coefficients. Energy and ma
ss balances are made at each time step to compute the bed pressure, ma
ss, adsorption level, and energy changes that occur during the adsorpt
ion and desorption process. Using these results, the thermodynamic per
formance of the heat pump is calculated. Results showing the heat pump
's performance and capacity as a function of the four major dimensionl
ess groups, DR, Pe, Ri, and KA(r), are presented.