Because it is not practical to analyze for each individual chemical co
mpound present in natural organic matter (NOM), surrogate characteriza
tion methods were sought that could identify interrelationships betwee
n NOM and its treatability. Source-related and seasonal differences, e
ffects of ozonation and coagulation on NOM, characterization of NOM in
sequential unit processes including granular activated carbon, and as
pects of bromide-NOM interactions are explored. Whereas coagulants rem
ove NOM intact, particularly higher-molecular-weight fractions, ozone
converts humic to nonhumic material, resulting in NOM fractions that c
ould be difficult to remove by subsequent coagulation. Bromide ion can
confound analytical interpretation of separation techniques unless th
e bromide concentration is equalized in the individual fractions.